Hydrogen peroxide is used as both an oxidiser and a monopropellant. Relatively high density and non-toxic, it was abandoned after early use in British rockets, but recently revived as a propellant for the Black Horse spaceplane. Hydrogen peroxide solutions are clear, astringent, colorless liquids which are slightly more viscous than water. They are described by Military Specification MIL-H-16005. High-strength hydrogen peroxide solutions are very reactive oxidising agents. Hydrogen peroxide is miscible in all proportions in water; it is soluble in a large number of organic liquids which are also soluble in water. However, many of these mixtures form explosive mixtures. Hydrogen peroxide-water solutions are normally insensitive to detonation by shock or impact. Surfaces that come in contact with hydrogen peroxide must be specially treated (passivated) before use, to prevent the decomposition of the hydrogen peroxide. Hydrogen peroxide-water solutions and their vapours are considered non-toxic, but are characterised by their ability to produce local irritation.
Hydrogen peroxide is manufactured commercially by several processes. Inorganic processes employ the electrolysis of an aqueous solution of sulphuric acid or acidic ammonium bisulphate, followed by hydrolysis of the peroxydisulfate which is formed. For reasons of economy and flexibility of plant location, organic processing methods have become important in the production of hydrogen peroxide. These include (1) the autoxidation of hydroquinone or one of its homologues in a suitable solvent system and (2) the partial gas-phase oxidation of hydrocarbons.
Dilute aqueous hydrogen peroxide is concentrated to about 90 per cent by conventional distillation. Higher-strength solutions are prepared by fractional crystallisation of 90 per cent feed stock. Estimated United States production for 1959 was 50,000 tonnes based upon 100 per cent hydrogen peroxide. In large quantities, 95 per cent hydrogen peroxide then cost approximately $1.00 per kg. In small drum lots, 98 per cent solutions cost $ 2.00 per kg. Density varies: 2.44 g/cc for 100% H2O2, 2.43 for 98%, 2.42 for 96%, 2.33 for 75%.
Hydyne was a propellant blend pushed rather vigorously by the Redstone arsenal in the late 1950's, but it found little application. Hydyne, which is also known as MAF-4, is a 60 per cent, by weight, mixture of UDMH and 40 weight percent diethyltrianine (DETA). The normally occurring impurities are dimethylamine, beta-aminoethyl-N-piperazine, and water. Hydyne is a clear, colourless liquid which may become discoloured on exposure to air during storage. Both UDMH and DETA have an ammoniacal odour; the odour is not so sharp or fishy as that of UDMH. Hydyne is a hygroscopic liquid which will absorb carbon dioxide and oxygen from air. It is completely miscible with water and ethanol; the solubility of gasoline and JP-4 in Hydyne are somewhat limited. It forms flammable explosive mixtures with air. Amines generally yellow during storage due to oxidation followed by polymerisation induced by air (O2)· reaction is believed to form an intermediate amine oxide which undergoes polymerisation. The cost of Hydyne in 1959 was $ 0.80 per kg.